To perform a redirect from domain.com to www.domain.com, insert the following code into your .htaccess file.
# mod_rewrite in use
Options +FollowSymlinks
RewriteEngine On
RewriteCond %{http_host} ^domain.com [NC]
RewriteRule ^(.*)$ http://www.domain.com/$1 [R=301,L]
To perform a redirect from www site to non-www site, use the following code in .htaccess file.
# mod_rewrite in use
Options +FollowSymLinks
RewriteEngine on
RewriteCond %{HTTP_HOST} .
RewriteCond %{HTTP_HOST} !^domain\.com
RewriteRule (.*) http://domain.com/$1 [R=301, [...]